İlk pilden sonra icat edilen piller arasında şunlar sayılabilir: Daniell pili. Leclanché hücresi. Nikel-kadmiyum pil. Kurşun-asit pil. Lityum-iyon pil. Ayrıca, 1912 yılında kimyager Gilbert Newton Lewis, ilk lityum-iyon pili üretmiştir.
Pili ilk bulan kişi İtalyan fizikçi Alessandro Volta'dır. Volta, 1800 yılında, birbirinden tuzlu suya batırılmış karton ya da bez katmanıyla ayrılan, üst üste yığılmış bir çift bakır ve çinko disklerinden oluşan "voltaik pil" olarak bilinen ilk gerçek bataryayı icat etmiştir.
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